of Petroleum and Petroleum Products (ASTM Practice. D ). MPMS Chapter Determination of Water in Crude Oil by the Distillation Method (ASTM Test. ASTM D Standard Test Method for WATER IN PETROLEUM PRODUCTS AND BITUMINOUS MATERIALS BY DISTILLATION. ASTM D Standard Test Method for Water in Petroleum Products and Bituminous Materials by Distillation.

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Condensed solvent and water are d9 separated in a trap, the water settling in the graduated section of the trap and the solvent returning to the still.

Always apply a very thin? Last previous edition approved in as D95— It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Distillation Flask Heater, ASTM D, ASTM D, ASTM D95, IP 74, ASTM E, IP , IP

The end-point determination in KF titration occurs by means of bivoltametric indication. The values in parentheses are for information only. The two types of volumetric KF differ in the exact composition of titrant and solvent.

Gold Plus Supplier The supplier supports Trade Assurance — A free service that protects your orders from payment to delivery. In other words, the larger the sample, the less error is introduced into the analysis by sample weighing, transfer and other handling. The supplier supports Trade Assurance — A asgm service that protects your orders from payment to delivery. If you feel that your comments have not received a fair hearing you should make your views known to the ASTM Committee on Standards, at the address shown below.


Chemistry and Principles Karl Fischer titration proceeds according to a reaction with a two-step mechanism in which sulfur dioxide initially reacts with an alcohol ROH to form an ester intermediate which is neutralized, or buffered, by an appropriate organic base RN.

More frequent cleaning is recommended if the nature of samples being run causes persistent contamination.

NOTE 3—Instead of standardizing on a particular apparatus speci? Volumetric or coulometric KF methods, utilizing either direct titration or the oil evaporator technique, can be used to quantify water in oil samples from trace amounts to percent.

Modern Instrumental Methods and Techniques.

Vessels c95, and mL nominal capacity have proved satisfactory. Once all the water has reacted with the iodine, trace quantities of free iodine appear in the titration cell, causing a drop in voltage necessary to keep the polarization current constant, which in turn signals the end-point of the titration.

Heating efficiency is promoted greatly with good contact between the heating element and the glass vessel. Understanding Oil’s Saturation Point.


D9 any drops of water adhering to the sides of the trap with a glass or polytetra? A number of lubricating oil additives are reactive and are known to interfere with direct KF titration.

Your comments will receive careful consideration at a meeting of the responsible technical committee, which you may attend. These include corrosion, erosion, etching and hydrogen embrittlement. D95 — 05 4. With both types of volumetric KF, imidazole is d9 base used most frequently as a buffer to maintain optimal pH for the reaction. This standard is subject to revision at any time by the responsible technical committee and must be reviewed every?


Recommended Sample Sizes for KF Analysis Sample Size Selection For both direct and indirect KF methods, sample size selection is critical for minimizing errors associated with sample weighing, transfer and injection.

Analyzing Water in Oil

Supplier Types Trade Assurance. Types of Titration Volumetric KF Volumetric KF proceeds in the conventional manner of a classic titration, in that the titrant containing iodine is added mechanically to the solvent containing the sample by the titrator’s burette Figure 1. Temperature is adjusted by a temperature control dial. However, neither of these methods can detect dissolved water or reproducibly detect trace levels of emulsified water. How is the technical services on the product9 Engineer available to service machinery overseas.

However, due to solubility and reactivity issues described above, analysts often drastically reduce sample size, which tends to reduce the reproducibility of test results. Coulometric KF is most accurate in the range of 1 ppm to 5 percent water.